蒎烯合成异松油烯的研究

    胡宏成， 曾 韬*， 陈华成（南京林业大学化学工程学院，江苏南京210037）
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    摘 要：采用对甲苯磺酸催化蒎烯合成异松油烯，在反应温度90℃，反应时间7 h，催化剂用量为原料质量的12.7 %，水用量为原料质量的36 %，乳化剂用量为原料质量的1.3 %，异松油烯的含量和得率分别达到38.8 %和39.9 %。其合成工艺和产品得率都优于和高于目前国内外现有同类研究水平。

    关键词：蒎烯；对甲苯磺酸；异松油烯

    中图分类号：TQ351       文献标识码：A       文章编号：1673-5854（2007）01-0019-03

Study on Synthesis of Terpinolene from Pinene
HU Hong-cheng,ZENG Tao,CHEN Hua-cheng
(College of Chemical Engineering,Nanjing Forestry University,Nanjing 210037,China )

Abstract: Terpinolene was synthesized from pinene by the catalysis of p-tolueresulfonic acid.The final content of terpinolene in product could be maintained 38.8 % and the yield of terpinolene was 39.9 %. Under the condition of 90 ℃，7 h,12.7 % catalyst, 36 % water,1.3 % emulsifier.The synthesis technigue and yield of product are all superior than those at home and abroad.
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Key words:  pinene;toluene-p-sulfonic acid;terpinolene